1In lg skillet, over med-high heat, brown chopss in oil. Pour off any fat. In bowl, combine brown sugar, cinnamon, cloves, tomato sauce, 1/4 cup reserved peach syrup and vinegar, mix well. Sprinkle pork chops w/ salt and peper. Arrange chops in slow-cooker, place peaches on top of chops. Pour tomato mix over all. Cover, cook on low for 4-6 hrs, or until pork is completely done.