Ultimate Double Chocolate Brownies

Ultimate Double Chocolate Brownies was pinched from <a href="http://moneysavingmom.com/2013/10/ultimate-double-chocolate-brownies.html" target="_blank">moneysavingmom.com.</a>
INGREDIENTS
¾ cup cocoa
½ teaspoon baking soda
2/3 cup melted butter, divided
½ cup boiling water
2 cups sugar
2 eggs
1 1/3 cups flour
1 teaspoon vanilla
¼ teaspoon salt
½ cup chopped pecans, optional
12 oz. package chocolate chips*
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