Arrange muffin quarters in single layer in greased 3 quart rectangular baking dish; set aside
Preheat oven to 350. In large bowl, beat together eggs, milk, chile peppers, salt and black pepper with rotary beater or whisk til well mixed. Pour egg mixture over muffin quarters; sprinkle with ham, green onions and olives. Top with roasted sweet peppers, provolone cheese and cheddar cheese.
Bake, uncovered, about 35 minutes til a knife inserted near center comes out clean. Let stand for 10 minutes before serving. Makes 10 to 12 servings
To make ahead, prepare as directed except do not preheat oven; cover with plastic wrap and chill for up to 24 hours. Uncover dish; discard plastic wrap. Cover dish with foil. Bake, uncovered in 350 oven about 45 minutes.