In a large bowl, combine flour, salt, baking powder, and baking soda. Using a pastry blender, cut in butter until mixture is crumbly.
In a small bowl, combine warm water and yeast, stirring to dissolve. Add sugar, stirring to dissolve. Let mixture stand for 5 minutes or until foamy. Add to flour mixture. Gradually add buttermilk, stirring to combine. Dough will be sticky. Cover and refrigerate overnight.
Spray a large baking sheet with nonstick cooking spray. On a lightly floured surface, turn out dough, and pat to ¾-inch thickness. Using a 2 1/2-inch round cutter, cut dough, rerolling scraps as needed. Place biscuits on prepared pan, and let stand at room temperature for 2 to 2 1/2 hours or until doubled in size.
Preheat oven to 425°. Bake biscuits for 10 minutes or until golden brown. Serve warm.
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