Heat 1/2 of oil in large pan. Sauté Brocolli, peppers and lemon zest together. Add 1 clove grated garlic. Cook until vegetables soften while stirring. Should take about 5 minutes. Remove vegetables to platter. Cover, and set aside.
Add remaining garlic to pan with olive oil. Add the shrimp. Cook and stir until shrimp is nearly cooked. will turn pink, and inside will Still be slightly shiny. Remove shrimp from pan.
Mix fish sauce and wine together. Add to the pan. Add crushed Red pepper, and basil, and lemon juice. Cook about 2 minutes on high heat stirring. Mix corn starch with 2 teaspoon of water. Add to pan.
Add shrimp and vegetables back to pan with sauce. Cook until thickened and shrimp is cooked through. About 2-3 minutes. Add capers, Salt and pepper to taste. Serve alone or over Cooked pasta.